Interdiffusion in Iron-Cobalt Alloys

" Catalytic Reactions on Iron / Cobalt and Iron / Nickel Alloys

First principles calculation of the interdiffusion coefficient in binary alloys.

The atomic mechanisms of diffusion in alloys are complex due to the variations of migration energies with environment and the correlations induced by short-range order between the different components. We present a first-principles approach for calculating vacancy-mediated diffusion coefficients in crystalline binary alloys and apply it to obtain the interdiffusion coefficient of Al(1-x)Lix. Th...

Interdiffusion of Refractory Elements in Fe-Cr-X (X-Mo, W) and Fe-Mo-W Ternary Iron Alloys

Interdiffusion coefficients of the refractory elements in Fe-Cr-X (X 1⁄4 Mo, W) and Fe-Mo-W ternary alloys were measured on the basis of the modified Boltzmann-Matano method for ternary systems. The cross interdiffusion coefficient, ~ D CrW was positive in Fe-Cr-W ternary alloy, indicating that W accelerates interdiffusion between Fe and Cr atoms. On the other hand, the cross interdiffusion coe...

The Structure of Intermediate Phases in Alloys of Titanium with Iron, Cobalt, and Nickel

The crystal structure of the intermediate phases in the binary systems of titanium with iron, cobalt, and nickel has been studied and the results compared with those previously published. The phases of the Ti2X type are face-centered cubic with % atoms per cell, and the TiX phases are body-centered cubic. TiFe, and Tic02 are hexagonal but not isomorphous. The nickel-rich phase has the compositi...

Mechanical Properties of Electroformed Nickel Cobalt Alloys

Mechanical properties of nickel-cobalt alloys (0-10% Co) electroformed with low internal stress in sulfamate-based solutions were investigated in as deposited and heat treated conditions. It was demonstrated that alloy properties can be modified by selecting deposition conditions and alloy composition. Recommendations on alloy selection are made based on application requirements. The higher str...